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How the Unit 6 practical paper works

Edexcel IAL Chemistry · WCH16 Practical Skills in Chemistry II

Unit 6 is the A2 written practical paper. It builds on Unit 3 but uses the techniques of Units 4 and 5, and expects more independent analysis of data you have not seen before.

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The paper

What the questions look like

A typical paper (January 2022) had four questions:

1. Inorganic analysis: complete a table of observations and inferences for an unknown salt, then suggest its formula.

2. Organic analysis: molecular formula from percentage composition and a mass spectrum, then deduce a structure from test results and IR data.

3. Titration and kinetics: make a standard solution, calculate the formula of a salt from a redox titration, then describe a continuous monitoring method and read rates from tangents.

4. Melting temperature: describe the procedure and what impurities do.

Questions are mostly 'describe', 'explain', 'justify', 'deduce' and 'calculate', and some ask for labelled diagrams or work drawn on a graph.

What examiners reward

From the October 2024 report:

Worked example

In an analysis table, a student adds aqueous sodium hydroxide to solution Y and sees a green precipitate that turns brown at the surface on standing. Write the observation and inference correctly.

  1. Observation (what is seen): green precipitate, turning brown on standing in air.
  2. Inference (what it shows): Fe2+ ions are present; the precipitate is Fe(OH)2, which is oxidised by air to Fe(OH)3.

Answer: Observation: green ppt turning brown. Inference: Fe2+ (Fe(OH)2 oxidised to Fe(OH)3).

Key idea: Unit 6: 1 h 20 min, 50 marks, A2 techniques plus all the AS tests. Use the data given, do not round early, know the technical terms and how each method is actually carried out.

Check yourself

  1. How long is the Unit 6 paper?
    • 1 hour 45 minutes
    • 2 hours
    • 50 minutes
    • 1 hour 20 minutes
    Show answer

    1 hour 20 minutes. It is 1 h 20 min for 50 marks, like Unit 3.

  2. What percentage of the International A2 (IA2) is Unit 6 worth?
    • 10%
    • 20%
    • 30%
    • 40%
    Show answer

    20%. 20% of the IA2 and 10% of the full A level.

  3. Which tests can appear on the Unit 6 paper as well as the A2 techniques?
    • Only tests for transition metal ions
    • No qualitative tests
    • Only the flame tests
    • The anion, cation, gas and organic group tests from Units 1 and 2
    Show answer

    The anion, cation, gas and organic group tests from Units 1 and 2. The specification says Unit 6 also assesses the Unit 1 and 2 tests.

  4. Which entry belongs in the 'observation' column of an analysis table?
    • Off-white precipitate that darkens on standing
    • Mn2+ ions present
    • Manganese(II) hydroxide forms
    • The solid is a transition metal compound
    Show answer

    Off-white precipitate that darkens on standing. Observations are what you see; the others are inferences.

  5. A student wants to find pKa for a weak acid with a pH meter. Which method is correct?
    • Put the pH meter in the mixture at the end point
    • Measure the pH of the alkali before the titration
    • Measure the pH when exactly half of the acid has been neutralised
    • Measure the pH after adding a large excess of alkali
    Show answer

    Measure the pH when exactly half of the acid has been neutralised. At the end point all the acid is neutralised; at half-neutralisation [HA] = [A-], so pH = pKa.

  6. Give two pieces of advice from examiners for the Unit 6 paper.
    Show answer

    Use the information given in the question, and set out calculations clearly without rounding part-way (also: learn technical terms, practise drawing apparatus).. These come straight from recent examiners' reports.

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Last updated 8 November 2026. Spotted a mistake? Tell us.